First perphenylated carbo-oligoacetylenes: an extension of the polytriacetylene family.
Identifieur interne : 002254 ( Main/Exploration ); précédent : 002253; suivant : 002255First perphenylated carbo-oligoacetylenes: an extension of the polytriacetylene family.
Auteurs : Arnaud Rives [France] ; Valérie Maraval ; Nathalie Saffon-Merceron ; Remi ChauvinSource :
- Chemistry (Weinheim an der Bergstrasse, Germany) [ 1521-3765 ] ; 2012.
Abstract
The first examples of a novel family of sp-carbon-rich n-π-conjugated oligomers/polymers, namely carbo-mers of polyacetylene, also referred to as "1,4-PTA" isomers of the classical polytriacetylenes (1,2-PTAs), are described in the perphenylated series. The two first representatives proved to be stable in solution, and exhibit a zig-zag arrangement in the crystal state. The third member of the family, isolated in SnCl(2) matrix, proved to be stable in the solid state and was characterized by MALDI-TOF MS, (1)H NMR, CPMAS (13)C NMR, and absorption spectroscopy. An explanation for its reactivity in solution is proposed. The chromophoric properties in the visible region are shown to vary significantly and consistently along the series.
DOI: 10.1002/chem.201201555
PubMed: 23018745
Affiliations:
Links toward previous steps (curation, corpus...)
- to stream PubMed, to step Corpus: 001D45
- to stream PubMed, to step Curation: 001D45
- to stream PubMed, to step Checkpoint: 001C81
- to stream Ncbi, to step Merge: 000998
- to stream Ncbi, to step Curation: 000998
- to stream Ncbi, to step Checkpoint: 000998
- to stream Main, to step Merge: 002279
- to stream Main, to step Curation: 002254
Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">First perphenylated carbo-oligoacetylenes: an extension of the polytriacetylene family.</title>
<author><name sortKey="Rives, Arnaud" sort="Rives, Arnaud" uniqKey="Rives A" first="Arnaud" last="Rives">Arnaud Rives</name>
<affiliation wicri:level="3"><nlm:affiliation>CNRS, Laboratoire de Chimie de Coordination, Toulouse, France.</nlm:affiliation>
<country xml:lang="fr">France</country>
<wicri:regionArea>CNRS, Laboratoire de Chimie de Coordination, Toulouse</wicri:regionArea>
<placeName><region type="region">Occitanie (région administrative)</region>
<region type="old region">Midi-Pyrénées</region>
<settlement type="city">Toulouse</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Maraval, Valerie" sort="Maraval, Valerie" uniqKey="Maraval V" first="Valérie" last="Maraval">Valérie Maraval</name>
</author>
<author><name sortKey="Saffon Merceron, Nathalie" sort="Saffon Merceron, Nathalie" uniqKey="Saffon Merceron N" first="Nathalie" last="Saffon-Merceron">Nathalie Saffon-Merceron</name>
</author>
<author><name sortKey="Chauvin, Remi" sort="Chauvin, Remi" uniqKey="Chauvin R" first="Remi" last="Chauvin">Remi Chauvin</name>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">PubMed</idno>
<date when="2012">2012</date>
<idno type="RBID">pubmed:23018745</idno>
<idno type="pmid">23018745</idno>
<idno type="doi">10.1002/chem.201201555</idno>
<idno type="wicri:Area/PubMed/Corpus">001D45</idno>
<idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">001D45</idno>
<idno type="wicri:Area/PubMed/Curation">001D45</idno>
<idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Curation">001D45</idno>
<idno type="wicri:Area/PubMed/Checkpoint">001C81</idno>
<idno type="wicri:explorRef" wicri:stream="Checkpoint" wicri:step="PubMed">001C81</idno>
<idno type="wicri:Area/Ncbi/Merge">000998</idno>
<idno type="wicri:Area/Ncbi/Curation">000998</idno>
<idno type="wicri:Area/Ncbi/Checkpoint">000998</idno>
<idno type="wicri:Area/Main/Merge">002279</idno>
<idno type="wicri:Area/Main/Curation">002254</idno>
<idno type="wicri:Area/Main/Exploration">002254</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en">First perphenylated carbo-oligoacetylenes: an extension of the polytriacetylene family.</title>
<author><name sortKey="Rives, Arnaud" sort="Rives, Arnaud" uniqKey="Rives A" first="Arnaud" last="Rives">Arnaud Rives</name>
<affiliation wicri:level="3"><nlm:affiliation>CNRS, Laboratoire de Chimie de Coordination, Toulouse, France.</nlm:affiliation>
<country xml:lang="fr">France</country>
<wicri:regionArea>CNRS, Laboratoire de Chimie de Coordination, Toulouse</wicri:regionArea>
<placeName><region type="region">Occitanie (région administrative)</region>
<region type="old region">Midi-Pyrénées</region>
<settlement type="city">Toulouse</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Maraval, Valerie" sort="Maraval, Valerie" uniqKey="Maraval V" first="Valérie" last="Maraval">Valérie Maraval</name>
</author>
<author><name sortKey="Saffon Merceron, Nathalie" sort="Saffon Merceron, Nathalie" uniqKey="Saffon Merceron N" first="Nathalie" last="Saffon-Merceron">Nathalie Saffon-Merceron</name>
</author>
<author><name sortKey="Chauvin, Remi" sort="Chauvin, Remi" uniqKey="Chauvin R" first="Remi" last="Chauvin">Remi Chauvin</name>
</author>
</analytic>
<series><title level="j">Chemistry (Weinheim an der Bergstrasse, Germany)</title>
<idno type="eISSN">1521-3765</idno>
<imprint><date when="2012" type="published">2012</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
</fileDesc>
<profileDesc><textClass></textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">The first examples of a novel family of sp-carbon-rich n-π-conjugated oligomers/polymers, namely carbo-mers of polyacetylene, also referred to as "1,4-PTA" isomers of the classical polytriacetylenes (1,2-PTAs), are described in the perphenylated series. The two first representatives proved to be stable in solution, and exhibit a zig-zag arrangement in the crystal state. The third member of the family, isolated in SnCl(2) matrix, proved to be stable in the solid state and was characterized by MALDI-TOF MS, (1)H NMR, CPMAS (13)C NMR, and absorption spectroscopy. An explanation for its reactivity in solution is proposed. The chromophoric properties in the visible region are shown to vary significantly and consistently along the series.</div>
</front>
</TEI>
<affiliations><list><country><li>France</li>
</country>
<region><li>Midi-Pyrénées</li>
<li>Occitanie (région administrative)</li>
</region>
<settlement><li>Toulouse</li>
</settlement>
</list>
<tree><noCountry><name sortKey="Chauvin, Remi" sort="Chauvin, Remi" uniqKey="Chauvin R" first="Remi" last="Chauvin">Remi Chauvin</name>
<name sortKey="Maraval, Valerie" sort="Maraval, Valerie" uniqKey="Maraval V" first="Valérie" last="Maraval">Valérie Maraval</name>
<name sortKey="Saffon Merceron, Nathalie" sort="Saffon Merceron, Nathalie" uniqKey="Saffon Merceron N" first="Nathalie" last="Saffon-Merceron">Nathalie Saffon-Merceron</name>
</noCountry>
<country name="France"><region name="Occitanie (région administrative)"><name sortKey="Rives, Arnaud" sort="Rives, Arnaud" uniqKey="Rives A" first="Arnaud" last="Rives">Arnaud Rives</name>
</region>
</country>
</tree>
</affiliations>
</record>
Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Sante/explor/MersV1/Data/Main/Exploration
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 002254 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 002254 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien |wiki= Sante |area= MersV1 |flux= Main |étape= Exploration |type= RBID |clé= pubmed:23018745 |texte= First perphenylated carbo-oligoacetylenes: an extension of the polytriacetylene family. }}
Pour générer des pages wiki
HfdIndexSelect -h $EXPLOR_AREA/Data/Main/Exploration/RBID.i -Sk "pubmed:23018745" \ | HfdSelect -Kh $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd \ | NlmPubMed2Wicri -a MersV1
This area was generated with Dilib version V0.6.33. |